Adderall XR 25 mg is an extended-release (ER) form of the drug to treat attention deficit hyperactivity disorder(ADHD). It has two main substances dextroamphetamine and amphetamine. Adderall XR 25 mg orange white pill contains inactive ingredients such as colloidal silicon dioxide, compressible sugar, corn starch, magnesium stearate, microcrystalline cellulose, and saccharin sodium.